The binary mixture of two hydrofluorocarbons,
R-125 and R-143a, behaves almost like an azeotrope
and has been considered as a promising refrigerant
to substitute R-502. In this paper, we present a
thermodynamic property model for the R-125^143a system,
which was developed on the basis of a new cubic equation
of state proposed in our previous publications.
The essential thermodynamic properties such as PVTx
properties, vapor-liquid equilibrium, enthalpy,
entropy, isobaric specific heat, and speed of sound
are well represented simultaneously by the new model
in the entire fluid-phase of the R-125^143a system
including the pure components. The model is valid for
any composition with thermodynamic consistency to cover
a range broad enough for refrigeration engineering
applications. A pressure-enthalpy diagram for the
R-125^143a mixture with 50 mass“ R-125 is also
presented.
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