| Specific Isochoric Heat Capacity Measurements for Liquid Isobutane@@ |
| Hiroyuki MIYAMOTOCHiroshi KITAJIMA, Noboru KAGAWACJoseph W.MAGEECSeizo TSURUNOCKoichi WATANABE |
Experimental specific isochoric heat capacitiesiCvjand PƒÏT@properties@for isobutane@are presented that were measured with a twin-cell type adiabatic isochoric calorimeter.The measurements were obtained for temperatures from 272 to 408K and for pressures up to 30 MPa.The sample purity was 99D99mol“DThe expanded uncertaintiesii.e.Ca coverage factor k2jare }13mK for temperatureC}8kPa for pressureC }0D16“ for densityCand}3D6“ for Cv in the liquid phaseD An evaluation and a comparison of the expenmental data with highly reliable equations of state confirmed satisfactorily the thermodynamic consistency of the present measurements. |